Methyl 3,3,3-trifluoro-2-oxopropanoate

Modify Date: 2024-01-03 12:07:36

Methyl 3,3,3-trifluoro-2-oxopropanoate Structure
Methyl 3,3,3-trifluoro-2-oxopropanoate structure
Common Name Methyl 3,3,3-trifluoro-2-oxopropanoate
CAS Number 13089-11-7 Molecular Weight 156.060
Density 1.4±0.1 g/cm3 Boiling Point 58.5±40.0 °C at 760 mmHg
Molecular Formula C4H3F3O3 Melting Point 84-86ºC
MSDS Chinese USA Flash Point -9.0±22.2 °C
Symbol GHS02
GHS02
Signal Word Warning

 Names

Name methyl trifluoropyruvate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.4±0.1 g/cm3
Boiling Point 58.5±40.0 °C at 760 mmHg
Melting Point 84-86ºC
Molecular Formula C4H3F3O3
Molecular Weight 156.060
Flash Point -9.0±22.2 °C
Exact Mass 156.003433
PSA 43.37000
LogP 1.04
Vapour Pressure 208.1±0.1 mmHg at 25°C
Index of Refraction 1.331
Storage condition Flammables area

 Safety Information

Symbol GHS02
GHS02
Signal Word Warning
Hazard Statements H226
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes C: Corrosive;F: Flammable;Xi: Irritant;
Risk Phrases R10
Safety Phrases S45-S36/37/39-S26-S16
RIDADR UN 1993 3/PG 3
WGK Germany 3
Packaging Group III
Hazard Class 3
HS Code 2918300090

 Synthetic Route

~92%

Methyl 3,3,3-trifluoro-2-oxopropanoate Structure

Methyl 3,3,3-tr...

CAS#:13089-11-7

Literature: Dolensky, Bohumil; Kvicala, Jaroslav; Palecek, Jiri; Paleta, Oldrich Journal of Fluorine Chemistry, 2002 , vol. 115, # 1 p. 67 - 74

~46%

Methyl 3,3,3-trifluoro-2-oxopropanoate Structure

Methyl 3,3,3-tr...

CAS#:13089-11-7

Literature: Journal of Fluorine Chemistry, , vol. 115, # 1 p. 67 - 74

~96%

Methyl 3,3,3-trifluoro-2-oxopropanoate Structure

Methyl 3,3,3-tr...

CAS#:13089-11-7

Literature: Lermontov, Sergey A.; Ushakova, Lyudmila L.; Kuryleva, Nina V. Journal of Fluorine Chemistry, 2008 , vol. 129, # 5 p. 332 - 334

~%

Methyl 3,3,3-trifluoro-2-oxopropanoate Structure

Methyl 3,3,3-tr...

CAS#:13089-11-7

Literature: Journal of Fluorine Chemistry, , vol. 115, # 1 p. 67 - 74

~%

Methyl 3,3,3-trifluoro-2-oxopropanoate Structure

Methyl 3,3,3-tr...

CAS#:13089-11-7

Literature: Doklady Chemistry, , vol. 169, p. 722 - 725 Doklady Akademii Nauk SSSR, , vol. 169, p. 594 - 597

~%

Methyl 3,3,3-trifluoro-2-oxopropanoate Structure

Methyl 3,3,3-tr...

CAS#:13089-11-7

Literature: Journal of Organic Chemistry USSR (English Translation), , vol. 19, # 8 p. 1563 - 1564 Zhurnal Organicheskoi Khimii, , vol. 19, # 8 p. 1761 - 1762

~%

Methyl 3,3,3-trifluoro-2-oxopropanoate Structure

Methyl 3,3,3-tr...

CAS#:13089-11-7

Detail
Literature: Journal of Fluorine Chemistry, , vol. 49, # 1 p. 43 - 66

~%

Detail
Literature: Journal of Fluorine Chemistry, , vol. 49, # 1 p. 43 - 66

 Customs

HS Code 2918300090
Summary 2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

 Articles6

More Articles
Methyl 3,3,3-trifluoropyruvate: an improved procedure starting from hexafluoropropene-1, 2-oxide; identification of byproducts. Dolenský B, et al.

J. Fluor. Chem. 115(1) , 67-74, (2002)

Methyl 3, 3, 3-trifluoropyruvate hemiaminals: Stability and transaminations. Dolenský B, et al.

J. Fluor. Chem. 126(5) , 745-751, (2005)

Fluorinated butanolides and butenolides: Part 8. 2-(Trifluoromethyl) butan-4-olides by synthesis from methyl 3, 3, 3-trifluoropyruvate as building block. Paleta O, et al.

J. Fluor. Chem. 111(2) , 175-184, (2001)

 Synonyms

Methyl 3,3,3-trifluoro-2-oxopropanoate
Propanoic acid, 3,3,3-trifluoro-2-oxo-, methyl ester
Methyl 3,3,3-trifluoropyruvate
Trifluoropyruvic Acid Methyl Ester
Methyl Trifluoropyruvate
MFCD00114936