4-Chlorophenyl methyl sulfide
Modify Date: 2024-01-04 18:39:19
4-Chlorophenyl methyl sulfide structure
|
Common Name | 4-Chlorophenyl methyl sulfide | ||
|---|---|---|---|---|
| CAS Number | 123-09-1 | Molecular Weight | 158.648 | |
| Density | 1.2±0.1 g/cm3 | Boiling Point | 222.4±23.0 °C at 760 mmHg | |
| Molecular Formula | C7H7ClS | Melting Point | N/A | |
| MSDS | Chinese | Flash Point | 90.0±19.8 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
| Name | 4-Chlorothioanisole |
|---|---|
| Synonym | More Synonyms |
| Density | 1.2±0.1 g/cm3 |
|---|---|
| Boiling Point | 222.4±23.0 °C at 760 mmHg |
| Molecular Formula | C7H7ClS |
| Molecular Weight | 158.648 |
| Flash Point | 90.0±19.8 °C |
| Exact Mass | 157.995697 |
| PSA | 25.30000 |
| LogP | 3.73 |
| Vapour Pressure | 0.2±0.4 mmHg at 25°C |
| Index of Refraction | 1.588 |
Synonym:4-Chlorothioanisol Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 22 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Harmful if swallowed. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Inhalation: May cause respiratory tract irritation. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use extinguishing media most appropriate for the surrounding fire. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 123-09-1: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: Clear colourless liquid Odor: stench pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 168 - 169 deg C @ 760mmHg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: 229 deg F ( 109.44 deg C) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: 1.2145g/cm3 @ 20C Molecular Formula: C7H7ClS Molecular Weight: 158.562 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Hydrogen chloride, carbon monoxide, oxides of sulfur, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 123-09-1: WQ3840000 LD50/LC50: CAS# 123-09-1: Draize test, rabbit, eye: 100 mg Mild; Oral, mouse: LD50 = 672 mg/kg; Oral, rat: LD50 = 400 mg/kg. Carcinogenicity: 4-Chlorophenyl methyl sulfide - Not listed by ACGIH, IARC, or NTP. Other: See actual entry in RTECS for complete information. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 22 Harmful if swallowed. Safety Phrases: WGK (Water Danger/Protection) CAS# 123-09-1: No information available. Canada CAS# 123-09-1 is listed on Canada's NDSL List. CAS# 123-09-1 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 123-09-1 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A |
CHEMICAL IDENTIFICATION
HEALTH HAZARD DATAACUTE TOXICITY DATA
|
| Symbol |
GHS07 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H302 |
| Personal Protective Equipment | Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| Hazard Codes | Xn:Harmful; |
| Risk Phrases | R22 |
| Safety Phrases | S23-S26-S36/37/39 |
| RIDADR | 2810 |
| WGK Germany | 3 |
| RTECS | WQ3840000 |
| Packaging Group | III |
| Hazard Class | 6.1(b) |
| HS Code | 2930909090 |
| Precursor 10 | |
|---|---|
| DownStream 9 | |
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CAS#:74362-50-8| HS Code | 2930909090 |
|---|---|
| Summary | 2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0% |
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Analysis of chlorophenylmethylsulfides in the urine of rats injected with chlorobenzene by high performance liquid chromatography.
Ind. Health 23(4) , 283-7, (1985)
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HPLC analysis of 4-chlorophenyl methyl sulphide and diphenyl sulphide and their corresponding sulphoxides and sulphones in rat liver microsomes.
J. Pharm. Biomed. Anal. 27(1-2) , 315-25, (2002) Simple high performance liquid chromatography (HPLC) methods for the analysis of 4-chlorophenyl methyl sulphide (CPMS), diphenyl sulphide (DPS) and their corresponding sulphoxide and sulphone metaboli... |
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Involvement of cytochrome P450 and the flavin-containing monooxygenase(s) in the sulphoxidation of simple sulphides in human liver microsomes.
Life Sci. 73(3) , 359-69, (2003) This study was conducted to examine the involvement of cytochrome P450 (CYP450) and the flavin-containing monooxygenase (FMO) in the sulphoxidation of ethyl methyl sulphide (EMS), 4-chlorophenyl methy... |
| Benzene, 1-chloro-4- (methylthio)- |
| 1-chloro-4-methylsulfanylbenzene |
| 1-Chloro-4-(methylthio)benzene |
| Methyl 4-chlorophenyl sulfide |
| MFCD00013643 |
| 1-Chloro-4-(methylsulfanyl)benzene |
| Benzene, 1-chloro-4-(methylthio)- |
| EINECS 204-600-5 |
| 4-Chlorophenyl methyl sulfide |
- Shanghai Jizhi Biochemical Technology Co., Ltd
- China
- Product Name: 4-Chlorophenyl methyl sulfide
- Price: ￥258.0/25g ￥88.0/5g
- Purity: 98.0%
- Stocking Period: 3 Day
- Contact: Liu jia
- Dayang Chem (Hangzhou) Co., Ltd.
- China
- Product Name: 4-Chlorothioanisole
- Price: $Inquiry/100g $Inquiry/1kg $Inquiry/100kg $Inquiry/1000kg
- Purity: 98.0%
- Stocking Period: Inquiry
- Contact: Ms Wang
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