4-[(tert-Butyldimethylsilyl)oxy]butan-2-one

Modify Date: 2024-01-14 17:33:31

4-[(tert-Butyldimethylsilyl)oxy]butan-2-one Structure
4-[(tert-Butyldimethylsilyl)oxy]butan-2-one structure
Common Name 4-[(tert-Butyldimethylsilyl)oxy]butan-2-one
CAS Number 120591-36-8 Molecular Weight 202.36600
Density N/A Boiling Point N/A
Molecular Formula C10H22O2Si Melting Point N/A
MSDS N/A Flash Point N/A

 Names

Name 4-{[Dimethyl(2-methyl-2-propanyl)silyl]oxy}-2-butanone
Synonym More Synonyms

 Chemical & Physical Properties

Molecular Formula C10H22O2Si
Molecular Weight 202.36600
Exact Mass 202.13900
PSA 26.30000
LogP 2.98730

 Synthetic Route

~98%

4-[(tert-Butyldimethylsilyl)oxy]butan-2-one Structure

4-[(tert-Butyld...

CAS#:120591-36-8

Literature: Imagawa, Hiroshi; Saijo, Hayato; Yamaguchi, Hitomi; Maekawa, Ken; Kurisaki, Takahiro; Yamamoto, Hirofumi; Nishizawa, Mugio; Oda, Masataka; Kabura, Michiko; Nagahama, Masahiro; Sakurai, Jun; Kubo, Miwa; Nakai, Megumi; Makino, Kosho; Ogata, Mitsuko; Takahashi, Hironobu; Fukuyama, Yoshiyasu Bioorganic and Medicinal Chemistry Letters, 2012 , vol. 22, # 5 p. 2089 - 2093

~94%

4-[(tert-Butyldimethylsilyl)oxy]butan-2-one Structure

4-[(tert-Butyld...

CAS#:120591-36-8

Literature: Schultz, Mitchell J.; Hamilton, Steven S.; Jensen, David R.; Sigman, Matthew S. Journal of Organic Chemistry, 2005 , vol. 70, # 9 p. 3343 - 3352

~91%

4-[(tert-Butyldimethylsilyl)oxy]butan-2-one Structure

4-[(tert-Butyld...

CAS#:120591-36-8

Literature: O'Brien, Matthew; Baxendale, Ian R.; Ley, Steven V. Organic Letters, 2010 , vol. 12, # 7 p. 1596 - 1598

~89%

4-[(tert-Butyldimethylsilyl)oxy]butan-2-one Structure

4-[(tert-Butyld...

CAS#:120591-36-8

Literature: Gregg, Brian T.; Golden, Kathryn C.; Quinn, John F. Journal of Organic Chemistry, 2007 , vol. 72, # 15 p. 5890 - 5893

~84%

4-[(tert-Butyldimethylsilyl)oxy]butan-2-one Structure

4-[(tert-Butyld...

CAS#:120591-36-8

Literature: Shibata, Takanori; Kanda, Kazumasa; Ueno, Yasunori; Fujiwara, Ryo Bulletin of the Chemical Society of Japan, 2006 , vol. 79, # 7 p. 1146 - 1147

~%

4-[(tert-Butyldimethylsilyl)oxy]butan-2-one Structure

4-[(tert-Butyld...

CAS#:120591-36-8

Literature: Kao, Chai-Lin; Kittleman, William; Zhang, Hua; Seto, Haruo; Liu, Hung-Wen Organic Letters, 2005 , vol. 7, # 25 p. 5677 - 5680

~%

4-[(tert-Butyldimethylsilyl)oxy]butan-2-one Structure

4-[(tert-Butyld...

CAS#:120591-36-8

Literature: Hobley, Gerard; Stuttle, Keith; Wills, Martin Tetrahedron, 2003 , vol. 59, # 26 p. 4739 - 4748

~%

4-[(tert-Butyldimethylsilyl)oxy]butan-2-one Structure

4-[(tert-Butyld...

CAS#:120591-36-8

Literature: Kao, Chai-Lin; Kittleman, William; Zhang, Hua; Seto, Haruo; Liu, Hung-Wen Organic Letters, 2005 , vol. 7, # 25 p. 5677 - 5680

~%

4-[(tert-Butyldimethylsilyl)oxy]butan-2-one Structure

4-[(tert-Butyld...

CAS#:120591-36-8

Literature: Antonsen, Oeyvind; Benneche, Tore; Gundersen, Lise-Lotte; Undheim, Kjell Acta Chemica Scandinavica, 1992 , vol. 46, # 2 p. 172 - 177

 Synonyms

4-t-butyldimethylsilyloxy-2-butynal