Chemical Name: (η⁵-Cyclopentadienyl)[N,N-dimethyl-Ν′-(2-pyridinylmethylidene)propane-1,3-diamine]ruthenium hexafluorophosphate
CAS Number: 1603164-23-3
Molecular Formula: C16H17F6N3PRu
Molecular Weight: 502.4
Create Date: 2023-01-18 14:29:30
Modify Date: 2023-01-18 14:29:30
Description (η5-Cyclopentadienyl)[N,N-dimethyl-N′-(2-pyridinylmethylidene)propane-1,3-diamine]ruthenium hexafluorophosphate is also referred to as Herzon reductive hydration catalyst. Herzon reductive hydration catalyst is a half-sandwich ruthenium complex. It is a tridentate nitrogen-based ligand containing a hemilabile 3-(dimethylamino)propyl group. It participates in the conversion of terminal alkynes to linear alcohols.Catalyst mediates the transformation of alkynes to alcohols through ananti-Markovnikov addition. This reaction occurs at room temperature with the use of formic acid to assist in the reduction of the intermediate aldehyde to the corresponding alcohol. Description (η5-Cyclopentadienyl)[N,N-dimethyl-N′-(2-pyridinylmethylidene)propane-1,3-diamine]ruthenium hexafluorophosphate is also referred to as Herzon reductive hydration catalyst. Herzon reductive hydration catalyst is a half-sandwich ruthenium complex. It is a tridentate nitrogen-based ligand containing a hemilabile 3-(dimethylamino)propyl group. It participates in the conversion of terminal alkynes to linear alcohols.Catalyst mediates the transformation of alkynes to alcohols through ananti-Markovnikov addition. This reaction occurs at room temperature with the use of formic acid to assist in the reduction of the intermediate aldehyde to the corresponding alcohol.