3-(tert-butyldimethylsilyloxy)glutaric anhydride
Names
[ CAS No. ]:
91424-40-7
[ Name ]:
3-(tert-butyldimethylsilyloxy)glutaric anhydride
[Synonym ]:
4-{[Dimethyl(2-methyl-2-propanyl)silyl]oxy}dihydro-2H-pyran-2,6(3H)-dione
2H-Pyran-2,6(3H)-dione, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]dihydro-
MFCD00075235
4-[tert-butyl(dimethyl)silyl]oxyoxane-2,6-dione
4-{[tert-Butyl(dimethyl)silyl]oxy}dihydro-2H-pyran-2,6(3H)-dione
Chemical & Physical Properties
[ Density]:
1.0±0.1 g/cm3
[ Boiling Point ]:
302.4±35.0 °C at 760 mmHg
[ Melting Point ]:
79-81 °C(lit.)
[ Molecular Formula ]:
C11H20O4Si
[ Molecular Weight ]:
244.360
[ Flash Point ]:
113.6±21.5 °C
[ Exact Mass ]:
244.113083
[ PSA ]:
52.60000
[ LogP ]:
1.55
[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C
[ Index of Refraction ]:
1.452
[ Storage condition ]:
2-8°C
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xi:Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S37/39
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ HS Code ]:
2931900090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2931900090
[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%
Articles
Bioconjug. Chem. 15(3) , 583-93, (2004)
We present a flexible and cost-efficient synthetic strategy for the preparation of a new family of phosphoramidite and solid-support reagents that can introduce a broad range of modifications into DNA...