(+)-DIMETHYL 2,3-O-BENZYLIDENE-D-TARTRATE

Names

[ Name ]:
(+)-DIMETHYL 2,3-O-BENZYLIDENE-D-TARTRATE

[Synonym ]:
dimethyl(4s,5s)-2-phenyl-1,3-dioxolane-4,5-dicarboxylate
(+)-Dimethyl 2,3-O-benzylidene-D-tartrate
(4S,5S)-2-Phenyl-1,3-dioxolane-4,5-dicarboxylic acid,dimethyl ester
(4S,5S)-dimethyl 2-phenyl-1,3-dioxolane-4,5-dicarboxylate
4S,5S-4,5-bis(methoxycarbonyl)-2-phenyl-1,3-dioxolane

Chemical & Physical Properties

[ Density]:
1.364g/cm3

[ Boiling Point ]:
409.3ºC at 760 mmHg

[ Melting Point ]:
74-76ºC(lit.)

[ Molecular Formula ]:
C₁₃H₁₄O₆

[ Molecular Weight ]:
266.24700

[ Flash Point ]:
158.7ºC

[ Exact Mass ]:
266.07900

[ PSA ]:
71.06000

[ LogP ]:
0.81520

[ Index of Refraction ]:
1.546

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Safety Phrases ]:
22-24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Precursor & DownStream

Precursor

DownStream

Articles

D. Seebach, E. Hungerbühler

Modern Synthetic Methods 2 , 91, (1980)

K. Fumita et al.

Tetrahedron Lett. 23 , 3507, (1982)

D.R. Williams, F.D. Klingler

Tetrahedron Lett. 28 , 869, (1987)