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2-Bromobenzoic acid

Names

[ CAS No. ]:
88-65-3

[ Name ]:
2-Bromobenzoic acid

[Synonym ]:
2-Brombenzoesure
EINECS 201-848-6
2-bromo-5-benzoic acid
RARECHEM AL BO 0014
QVR BE
EINECS2
Benzoic acid, 2-bromo-
2-Bromobenzoic acid
Brombenzoicacid
2-BROMOBENZOIC ACID FOR SYNTHESIS
2-Bromobenzoicacid
bromobenzoicacid
2-BROMOANISOLE
ortho-bromobenzoic acid
O-BROMO BENZOIC ACID
o-Bromobenzoic acid
o-bromo-benzoicaci
2-Bromobenzoicaicd
BROMO BENZOIC ACID, O-
MFCD00002402
2-BROMO BENZOIC ACID
2-Br-Ph-COOH
2-bromo-benzoicaci

Chemical & Physical Properties

[ Density]:
1.7±0.1 g/cm3

[ Boiling Point ]:
296.4±23.0 °C at 760 mmHg

[ Melting Point ]:
147-150 °C(lit.)

[ Molecular Formula ]:
C7H5BrO2

[ Molecular Weight ]:
201.017

[ Flash Point ]:
133.1±22.6 °C

[ Exact Mass ]:
199.947281

[ PSA ]:
37.30000

[ LogP ]:
2.15

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.608

[ Water Solubility ]:
slightly soluble

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
DG4448035
CHEMICAL NAME :
Benzoic acid, o-bromo-
CAS REGISTRY NUMBER :
88-65-3
BEILSTEIN REFERENCE NO. :
0971266
LAST UPDATED :
199710
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C7-H5-Br-O2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NCNSA6 National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. (Washington, DC) Volume(issue)/page/year: 5,7,1953

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36

[ Safety Phrases ]:
S26-S36-S24/25-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
DG4448035

[ Packaging Group ]:
II; III

[ Hazard Class ]:
5.1

[ HS Code ]:
29163900

Synthetic Route

Precursor & DownStream

Customs

[ HS Code ]: 2916399090

[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

An efficient palladium-benzimidazolyl phosphine complex for the Suzuki-Miyaura coupling of aryl mesylates: facile ligand synthesis and metal complex characterization.

Chem. Commun. (Camb.) 48 , 1967, (2012)

A new class of easily accessible hemilabile benzimidazolyl phosphine ligands has been developed. The ligand skeleton is prepared from commercially available and inexpensive o-phenylenediamine and 2-br...

Synthesis and cytotoxic activity of benzophenanthrolinone analogues of acronycine.

Chem. Pharm. Bull. 49(9) , 1077-80, (2001)

Condensation of either 2-bromobenzoic acid (4) or 2-chloro-3-nitrobenzoic acid (5) with suitable aminoquinolines 6-8 afforded phenylquinolylamines 9-13. Acid mediated cyclization gave the correspondin...

Degradation of 2-bromo-, 2-chloro- and 2-fluorobenzoate by Pseudomonas putida CLB 250.

FEMS Microbiol. Lett. 51(1) , 143-7, (1989)

Pseudomonas putida strain CLB 250 (DSM 5232) utilized 2-bromo-, 2-chloro- and 2-fluorobenzoate as sole source of carbon and energy. Degradation is suggested to be initiated by a dioxygenase liberating...


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