Phosphorus
Controlled Substances
Names
[ CAS No. ]:
7723-14-0
[ Name ]:
Phosphorus
[Synonym ]:
anhydrous phosphine
Amidophosphorsaeure-monoaethylester
Phosphorus
hydrogen phosphide
phosphorane acid
ethylphosphoramidate
phosphorane 28-cis
O-Ethylphosphoramidat
phosphorane
ethyl hydrogen phosphoramidate
Phosphoramidic acid,monoethyl ester
EINECS 231-768-7
MFCD00133771
Chemical & Physical Properties
[ Density]:
2.34 g/mL at 25 °C(lit.)
[ Boiling Point ]:
-87.2±9.0 °C at 760 mmHg
[ Melting Point ]:
280 °C (white)(lit.)
[ Molecular Formula ]:
P
[ Molecular Weight ]:
30.974
[ Flash Point ]:
30°C
[ Exact Mass ]:
30.973761
[ PSA ]:
13.59000
[ LogP ]:
0.05810
[ Vapour density ]:
0.02 (vs air)
[ Vapour Pressure ]:
27274.0±0.1 mmHg at 25°C
[ Stability ]:
Stable. Highly flammable. Incompatible with strong oxidizing agents, strong bases. Light and heat sensitive.
[ Water Solubility ]:
insoluble
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- TH3495000
- CHEMICAL NAME :
- Phosphorus (red)
- CAS REGISTRY NUMBER :
- 7723-14-0
- LAST UPDATED :
- 199710
- DATA ITEMS CITED :
- 33
- MOLECULAR FORMULA :
- P
- MOLECULAR WEIGHT :
- 30.97
- WISWESSER LINE NOTATION :
- .P RED
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Unreported
- SPECIES OBSERVED :
- Human - man
- DOSE/DURATION :
- 4412 ug/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 85DCAI "Poisoning; Toxicology, Symptoms, Treatments," 2nd ed., Arena, J.M., Springfield, IL, C.C. Thomas, 1970 Volume(issue)/page/year: 2,73,1970 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.1 mg/m3 JAN 1993 OEL-AUSTRALIA:TWA 0.1 mg/m3 JAN 1993 OEL-BELGIUM:TWA 0.1 mg/m3 JAN 1993 OEL-DENMARK:TWA 0.1 mg/m3 JAN 1993 OEL-FINLAND:STEL 0.1 mg/m3;Skin JAN 1993 OEL-FRANCE:TWA 0.1 mg/m3;STEL 0.3 mg/m3 JAN 1993 OEL-GERMANY:TWA 0.1 mg/m3 JAN 1993 OEL-HUNGARY:TWA 0.3 mg/m3;STEL 0.06 mg/m3 JAN 1993 OEL-JAPAN:TWA 0.1 mg/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 0.1 mg/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 0.1 mg/m3 JAN 1993 OEL-POLAND:TWA 0.3 mg/m3 JAN 1993 OEL-RUSSIA:STEL 0.03 mg/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.1 mg/m3;STEL 0.2 mg/m3 JAN 1993 OEL-THAILAND:TWA 0.1 mg/m3 JAN 1993 OEL-TURKEY:TWA 0.1 mg/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.1 mg/m3;STEL 0.3 mg/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M0004 No. of Facilities: 38 (estimated) No. of Industries: 2 No. of Occupations: 3 No. of Employees: 205 (estimated) NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M0005 No. of Facilities: 41 (estimated) No. of Industries: 1 No. of Occupations: 5 No. of Employees: 626 (estimated) NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 81650 No. of Facilities: 1187 (estimated) No. of Industries: 19 No. of Occupations: 42 No. of Employees: 13630 (estimated) NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 81684 No. of Facilities: 47 (estimated) No. of Industries: 3 No. of Occupations: 4 No. of Employees: 261 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M0004 No. of Facilities: 75 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 675 (estimated) No. of Female Employees: 225 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M0005 No. of Facilities: 6 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 91 (estimated) No. of Female Employees: 6 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 81650 No. of Facilities: 12775 (estimated) No. of Industries: 104 No. of Occupations: 88 No. of Employees: 208975 (estimated) No. of Female Employees: 7598 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 81684 No. of Facilities: 139 (estimated) No. of Industries: 5 No. of Occupations: 10 No. of Employees: 2924 (estimated) No. of Female Employees: 67 (estimated)
Safety Information
[ Symbol ]:
GHS02
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H228-H412
[ Precautionary Statements ]:
P210-P370 + P378
[ Personal Protective Equipment ]:
Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
[ Hazard Codes ]:
F,C,N,T+
[ Risk Phrases ]:
R11
[ Safety Phrases ]:
S7-S43-S61-S43C-S45-S38-S26-S5-S27-S6
[ RIDADR ]:
UN 1338 4.1/PG 3
[ WGK Germany ]:
2
[ RTECS ]:
TH3495000
[ Packaging Group ]:
III
[ Hazard Class ]:
4.1
[ HS Code ]:
2804709010
Customs
[ HS Code ]: 2804709010