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Zirconium(II) hydride

Names

[ CAS No. ]:
7704-99-6

[ Name ]:
Zirconium(II) hydride

[Synonym ]:
MFCD00148878
EINECS 231-727-3

Chemical & Physical Properties

[ Density]:
5.6 g/cm3 (20ºC)

[ Melting Point ]:
1857ºC

[ Molecular Formula ]:
Zr

[ Molecular Weight ]:
91.22400

[ Exact Mass ]:
89.90470

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
ZH8015000
CHEMICAL NAME :
Zirconium hydride
CAS REGISTRY NUMBER :
7704-99-6
LAST UPDATED :
199712
DATA ITEMS CITED :
24
MOLECULAR FORMULA :
H2-Zr
MOLECULAR WEIGHT :
93.24

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intratracheal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
45 gm/kg/26W-I
TOXIC EFFECTS :
Blood - other changes Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - dehydrogenases
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 37(7),36,1972 *** REVIEWS *** ACGIH TLV-TWA 5 mg(Zr)/m3; STEL 10 mg(Zr)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 5 mg(Zr)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,285,1971 OSHA PEL (Gen Indu):8H TWA 5 mg(Zr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 5 mg(Zr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 5 mg(Zr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 5 mg(Zr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 5 mg(Zr)/m3;STEL 10 mg(Zr)/m3 JAN 1993 OEL-BELGIUM:TWA 5 mg(Zr)/m3;STEL 10 mg(Zr)/m3 JAN 1993 OEL-DENMARK:TWA 5 mg(Zr)/m3 JAN 1993 OEL-FINLAND:TWA 5 mg(Zr)/m3 JAN 1993 OEL-GERMANY:TWA 5 mg(Zr)/m3 JAN 1993 OEL-HUNGARY:STEL 5 mg(Zr)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 5 mg(Zr)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 5 mg(Zr)/m3 JAN 1993 OEL-SWITZERLAND:TWA 5 mg(Zr)/m3 JAN 1993 OEL-TURKEY:TWA 5 mg(Zr)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 5 mg(Zr)/m3;STEL 10 mg(Zr)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 82060 No. of Facilities: 100 (estimated) No. of Industries: 2 No. of Occupations: 3 No. of Employees: 242 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 82060 No. of Facilities: 37 (estimated) No. of Industries: 2 No. of Occupations: 2 No. of Employees: 44 (estimated) No. of Female Employees: 5 (estimated)

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H228-H315-H319-H335

[ Precautionary Statements ]:
P210-P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
F+

[ Risk Phrases ]:
11-36/37/38

[ Safety Phrases ]:
S43-S24/25

[ RIDADR ]:
UN 1437 4.1/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
ZH8015000

[ Packaging Group ]:
II

[ Hazard Class ]:
4.1