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2-Bromopropane

Names

[ CAS No. ]:
75-26-3

[ Name ]:
2-Bromopropane

[Synonym ]:
i-propyl bromide
2-Brompropan
iso-C3H7Br
2-bromo-propane
2-bromo-propan
sec-Propyl bromide
2-propyl bromide
PropylBromide~
isopropyl-bromide
MFCD00000147
bromo-2propane
EINECS 200-855-1
propane,2-bromo

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
60.6±8.0 °C at 760 mmHg

[ Melting Point ]:
-89 °C

[ Molecular Formula ]:
C3H7Br

[ Molecular Weight ]:
122.992

[ Flash Point ]:
19.4±0.0 °C

[ Exact Mass ]:
121.973106

[ LogP ]:
2.03

[ Vapour Pressure ]:
205.0±0.1 mmHg at 25°C

[ Index of Refraction ]:
1.429

[ Stability ]:
Stable. Flammable. Incompatible with strong oxidizing agents.

[ Water Solubility ]:
0.3 g/100 mL

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TX4111000
CHEMICAL NAME :
Propane, 2-bromo-
CAS REGISTRY NUMBER :
75-26-3
LAST UPDATED :
199712
DATA ITEMS CITED :
8
MOLECULAR FORMULA :
C3-H7-Br
MOLECULAR WEIGHT :
123.01
WISWESSER LINE NOTATION :
EY1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
4837 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 20(12),52,1976
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Mammal - species unspecified
DOSE/DURATION :
36 gm/m3
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 18(4),55,1974 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
172 gm/m3/30M/1W-I
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - other changes Blood - hemorrhage
REFERENCE :
JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 80,139,1944 ** REPRODUCTIVE DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intraperitoneal
DOSE :
18900 mg/kg
SEX/DURATION :
female 14 day(s) pre-mating female 7 day(s) after conception
TOXIC EFFECTS :
Reproductive - Maternal Effects - ovaries, fallopian tubes Reproductive - Maternal Effects - menstrual cycle changes or disorders
REFERENCE :
INHEAO Industrial Health. (National Institute of Industrial Health, 6-21-1 Nagao, Tama-ku, Kawasaki, 213 Japan) V.1- 1963- Volume(issue)/page/year: 35,278,1997 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4017 No. of Facilities: 17 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 1582 (estimated) No. of Female Employees: 323 (estimated)

Safety Information

[ Symbol ]:

GHS02, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H360F-H373

[ Supplemental HS ]:
Repeated exposure may cause skin dryness or cracking.

[ Precautionary Statements ]:
P201-P210-P308 + P313

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
F:Flammable

[ Risk Phrases ]:
R11;R48/20;R60;R66

[ Safety Phrases ]:
S53-S16-S45

[ RIDADR ]:
UN 2344 3/PG 2

[ WGK Germany ]:
1

[ RTECS ]:
TX4111000

[ Packaging Group ]:
II

[ Hazard Class ]:
3

[ HS Code ]:
2930909090

Synthetic Route

Precursor & DownStream

Customs

[ HS Code ]: 2930909090

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

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