2-(TERT-BUTYLDIMETHYLSILOXY)PENT-2-EN-4-ONE

Names

[ Name ]:
2-(TERT-BUTYLDIMETHYLSILOXY)PENT-2-EN-4-ONE

[Synonym ]:
t-Butyldimethylsilylacetylacetonate
Butyldimethylsiloxypentenone
2-(T-BUTYLDIMETHYLSILOXY)PENT-2-EN-4-ONE
2,4-pentane dione t butyl dimethyl silyl enol ether
2-(T-BUTYLDIMETHYLSILOXY)-PENT-3-EN-4-ONE
(3E)-4-{[Dimethyl(2-methyl-2-propanyl)silyl]oxy}-3-penten-2-one
acetylacetone tert-butyldimethylsilyl enol ether
3-Penten-2-one, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-, (3E)-
ACETYLACETONE ENOL TERT-BUTYLDIMETHYLSILYL ETHER
4-(tert-butyldimethylsilyloxy)-3-penten-2-one
MFCD00010655
4-tert-Butyldimethylsiloxy-3-penten-2-one,mixture of isomers
4-TERT-BUTYLDIMETHYLSILOXY-3-PENTEN-2-ONE
2-[(tert-Butyldimethylsilyl)oxy]-2-penten-4-one

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
284.4±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C₁₁H₂₂O₂Si

[ Molecular Weight ]:
214.377

[ Flash Point ]:
80.6±0.0 °C

[ Exact Mass ]:
214.138901

[ PSA ]:
26.30000

[ LogP ]:
3.47

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.435

[ Storage condition ]:
2~8℃，Seal

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36/37/39

[ RIDADR ]:
1993

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

Synthetic Route

Click to get detail synthetic route

Articles

Synthesis of novel 13-methyl-13-dihydroanthracyclines.

Chem. Pharm. Bull. 34 , 4613, (1986)

T. Veysoglu, L.A. Mitscher

Tetrahedron Lett. 22 , 1299, (1981)