Ethyl 2-methylacetoacetate

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
185.8±8.0 °C at 760 mmHg

[ Melting Point ]:
-45 °C

[ Molecular Formula ]:
C₇H₁₂O₃

[ Molecular Weight ]:
144.168

[ Flash Point ]:
68.9±18.5 °C

[ Exact Mass ]:
144.078644

[ PSA ]:
43.37000

[ LogP ]:
1.06

[ Vapour Pressure ]:
0.7±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.414

[ Storage condition ]:
-20°C Freezer

[ Water Solubility ]:
IMMISCIBLE

Click to get detail MSDS

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
1993

[ WGK Germany ]:
3

[ HS Code ]:
2918300090

Click to get detail synthetic route

Precursor

DownStream

[ HS Code ]: 2918300090

[ Summary ]:
2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Asymmetric reduction of ethyl 2-methyl 3-oxobutanoate by Chlorella.

Biosci. Biotechnol. Biochem. 63(3) , 598-601, (1999)

Chlorella pyrenoidosa Chick reduced ethyl 2-methyl 3-oxobutanoate to the corresponding alcohols with the diastereomer (anti/syn) ratio of 53/47. The enantiomer excesses of anti-(2S, 3S)- and syn-(2S, ...

Asymmetric reduction of ethyl 2-methyl e-oxobutanoate by fungi.

Biosci. Biotechnol. Biochem. 64(1) , 194-7, (2000)

Seven fungi, which are found to reduce ethyl 3-oxobutanoate in high yields, were tested for their reducing ability for ethyl 2-methyl 3-oxobutanoate. We obtained some interesting findings. In particul...

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