Etrimfos
Names
[ CAS No. ]:
38260-54-7
[ Name ]:
Etrimfos
[Synonym ]:
O,O-dimethyl O-6-ethoxy-2-ethylpyrimidin-4-yl phosphorothioate
Satisfar DP-2
Etrimphos
(6-ethoxy-2-ethylpyrimidin-4-yl)oxy-dimethoxy-sulfanylidene-λ<sup>5</sup>-phosphane
O-(6-ethoxy-2-ethyl-4-pyrimidinyl) O,O-dimethyl phosphorothioate
Ekamet G
MFCD00055516
Satisfar
Ekamet ULV
Ekamet
O-6-ethoxy-2-ethylpyrimidin-4-yl O,O-dimethyl phosphorothioate
ETRIMFOS
EINECS 253-855-9
Satisfar LS 5
Caswell No. 365AAA
O-(6-ethoxy-2-ethylpyrimidin-4-yl) O,O-dimethyl phosphorothioate
Satisfar LS 3
Chemical & Physical Properties
[ Density]:
1.246g/cm3
[ Boiling Point ]:
352.6ºC at 760mmHg
[ Melting Point ]:
-3.35℃
[ Molecular Formula ]:
C10H17N2O4PS
[ Molecular Weight ]:
292.29200
[ Flash Point ]:
167ºC
[ Exact Mass ]:
292.06500
[ PSA ]:
104.60000
[ LogP ]:
2.98440
[ Appearance of Characters ]:
liquid
[ Index of Refraction ]:
1.528
[ Storage condition ]:
APPROX 4°C
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- TF8350000
- CHEMICAL NAME :
- Phosphorothioic acid, O,O-dimethyl O-(6-ethoxy-2-ethyl-4-pyrimidinyl) ester
- CAS REGISTRY NUMBER :
- 38260-54-7
- LAST UPDATED :
- 199204
- DATA ITEMS CITED :
- 4
- MOLECULAR FORMULA :
- C10-H17-N2-O4-P-S
- MOLECULAR WEIGHT :
- 292.32
- WISWESSER LINE NOTATION :
- T6N CNJ B2 DOPS&O1&O1 FO2
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1800 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 85ARAE "Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revision Volume(issue)/page/year: 1,137,1977
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- >2 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,358,1991
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 437 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- PBICDJ Proceedings of the British Insecticide and Fungicide Conference. V-8, 1961-75. For Publisher information, See PBCDDQ Volume(issue)/page/year: 2,675,1975
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- >500 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,358,1991
Safety Information
[ Symbol ]:
GHS06, GHS09
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H302-H311-H410
[ Precautionary Statements ]:
P273-P280-P301 + P312 + P330-P302 + P352 + P312-P391-P501
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xn: Harmful;N: Dangerous for the environment;
[ Risk Phrases ]:
22-50/53
[ Safety Phrases ]:
60-61
[ RIDADR ]:
UN3082 9/PG 3
[ RTECS ]:
TF8350000
[ HS Code ]:
2933599011
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2933599011
[ Summary ]:
2933599011 o-(2-(diethylamino)-6-methylpyrimidin-4-yl) o,o-dimethyl phosphorothioate。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:20.0%
Articles
Vopr. Pitan. (3) , 70-1, (1984)
Pesticide confirmation by triple stage quadrupole mass spectrometry: etrimfos and dimethoate.
J. Assoc. Off. Anal. Chem. 70(5) , 858-62, (1987)
The production of a protonated molecular ion, MH+, for a pesticide under investigation is often preferred for primary identification purposes. However, the lack of fragment ions under such chemical io...