2'-(dimethylamino)-2-biphenylyl-palladium(ii) chloride dinorbornylphosphine complex
Names
[ CAS No. ]:
359803-53-5
[ Name ]:
2'-(dimethylamino)-2-biphenylyl-palladium(ii) chloride dinorbornylphosphine complex
[Synonym ]:
benzo[1,3,2]dioxaphosphol-2-yl-dimethyl-amine
2-Dimethylamino-1,3,2-benzodioxaphosphol
2-dimethylamino-4,5-benzo-1,3,2-dioxaphospholane
2-dimethylamino-1,3,2-benzodioxaphosphole
MFCD03427335
2'-(dimethylamino)-2-biphenylyl-palladium(ll) chloride dinorbornylphosphine complex
2'-(dimethylamino)-2-biphenylyl-palladium(II) chloride dinorbornylphosphine complex
C12H8N(CH3)2PdClHP(2-norbornyl)2
chloro[2'-(dimethylamino)-2-biphenylyl]palladium-(1R,4S)-bicyclo[2.2.1]hept-2-yl[(1S,4R)-bicyclo[2.2.1]hept-2-yl]phosphane
Phosphorigsaeure-o-phenylenester-dimethylamid
2'-(dimethylamino)-2-biphenyl-palladium (II) chloride dinorbornylphosphine complex
2'-(dimethylamino)-2-biphenylpalladium(II) chloride dinorbornylphosphine
1,3,2-Benzodioxaphosphol-2-amine,N,N-dimethyl
Chemical & Physical Properties
[ Melting Point ]:
160-170ºC (dec.)(lit.)
[ Molecular Formula ]:
C28H37ClNPPd
[ Molecular Weight ]:
560.44700
[ Exact Mass ]:
559.13900
[ PSA ]:
16.83000
[ LogP ]:
7.95140
[ Appearance of Characters ]:
Powder | beige
MSDS
Safety Information
[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
[ RIDADR ]:
NONH for all modes of transport
[ HS Code ]:
28439000
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Articles
J. Am. Chem. Soc. 129 , 6931, (2007)
A catalyst system was identified which promotes the Heck coupling of nonactivated vinyl phosphates with electron deficient alkenes providing a new entry to diene products from simple and readily acces...
A new generation of air stable, highly active Pd complexes for C--C and C--N coupling reactions with aryl chlorides.Angew. Chem. Int. Ed. Engl. 41 , 3668, (2002)
S.C. Stinson
Chem. Eng. News october 29 , 23, (2001)