Tris[N,N-bis(trimethylsilyl)amide]gadolinium(III)

Names

[ Name ]:
Tris[N,N-bis(trimethylsilyl)amide]gadolinium(III)

[Synonym ]:
MFCD03427091
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, gadolinium salt (3:1)
Gadolinium tris(1,1,1,3,3,3-hexamethyldisilazan-2-ide)

Chemical & Physical Properties

[ Boiling Point ]:
126ºC at 760 mmHg

[ Melting Point ]:
67-90ºC(lit.)

[ Molecular Formula ]:
C₁₈H₅₄GdN₃Si₆

[ Molecular Weight ]:
638.404

[ Flash Point ]:
36 °F

[ Exact Mass ]:
638.217407

[ PSA ]:
9.72000

[ LogP ]:
7.26750

Safety Information

[ Symbol ]:

GHS02, GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H228-H261-H314

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P210-P231 + P232-P280-P305 + P351 + P338-P310-P422

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
F: Flammable;C: Corrosive;

[ Risk Phrases ]:
11-14/15-34

[ Safety Phrases ]:
16-26-36/37/39-43-45-7/8

[ RIDADR ]:
UN 3396 4.3/PG 2

[ Packaging Group ]:
III

[ Hazard Class ]:
4.1

Articles

Effect of concentration of trimethylchlorosilane (TMCS) and hexamethyldisilazane (HMDZ) silylating agents on surface free energy of silica aerogels.

J. Colloid. Interface Sci. 356(1) , 298-302, (2011)

The surface free energy of a solid determines its surface and interfacial behavior in processes like wetting and adhesion which is crucial for silica aerogels in case of organic liquid absorption and ...

A facile two-step dipping process based on two silica systems for a superhydrophobic surface.

Chem. Commun. (Camb.) 47(38) , 10761-3, (2011)

A silica microsphere suspension and a silica sol are employed in a two-step dipping process for the preparation of a superhydrophobic surface. It's not only a facile way to achieve the lotus effect, b...

Trimethylsilylation of cellulose in ionic liquids.

Macromol. Biosci. 9(4) , 369-75, (2009)

Trimethylsilylation of cellulose in different 1,3-dialkylimidazolium ionic liquids (IL) with hexamethyldisilazane (HMDS) as a silylating agent was investigated. Trimethylsilyl (TMSi) cellulose with a ...