Nickel(2+) acetylacetonate

Names

[ Name ]:
Nickel(2+) acetylacetonate

[Synonym ]:
Nickel(II) Acetylacetonate
anhydrous nickel acetylacetonate
3-Penten-2-one, 4-hydroxy-, nickel(2+) salt, (3Z)- (2:1)
Acetylacetonenickel
Nickel bis(acetylacetonate)
2,4-Pentanedione nickel(II) derivative
NICKEL PENTANEDIONATE
NICKEL ACETYLACETONATE
EINECS 221-875-7
Nickel(2+) bis[(2Z)-4-oxo-2-penten-2-olate]
MFCD00000024
Acetylacetonate nickel
Nickel(2+) bis[(2Z)-4-oxopent-2-en-2-olate]
Bis(acetylacetonato)nickel(II)
Nickel(2+) acetylacetonate
Acetylacetonato nickel
Bis(2,4-pentanedionato)nickel(II)
Nickel acetonylacetonate

Chemical & Physical Properties

[ Density]:
0,145 g/cm3

[ Boiling Point ]:
220 °C (11 mmHg)

[ Melting Point ]:
230 °C (dec.)(lit.)

[ Molecular Formula ]:
C₁₀H₁₄NiO₄

[ Molecular Weight ]:
256.909

[ Flash Point ]:
>200°C

[ Exact Mass ]:
256.024567

[ PSA ]:
52.60000

[ LogP ]:
1.92020

[ Index of Refraction ]:
1.57-1.64

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: SA2100000

CHEMICAL NAME :: 2,4-Pentanedione, nickel(II) deriv.

CAS REGISTRY NUMBER :: 3264-82-2

LAST UPDATED :: 199712

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C10-H14-Ni-O4

MOLECULAR WEIGHT :: 256.95

WISWESSER LINE NOTATION :: 1V1V1 &-NI-

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 125 mg/kg

REFERENCE :: CBCCT* "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. (National Academy of Science Library, 2101 Constitution Ave., NW, Washington, DC 20418) Volume(issue)/page/year: 4,231,1952 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO NICKEL, INORGANIC-air:10H CA TWA 0.015 mg(Ni)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X5635 No. of Facilities: 274 (estimated) No. of Industries: 2 No. of Occupations: 7 No. of Employees: 3418 (estimated) No. of Female Employees: 1678 (estimated)

Safety Information

[ Symbol ]:

GHS07, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302-H317-H350

[ Precautionary Statements ]:
P201-P280-P301 + P312 + P330-P308 + P313

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R22;R40;R43

[ Safety Phrases ]:
53-36/37/39-45-36/37

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
SA2100000

[ HS Code ]:
29420000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2918300090

[ Summary ]:
2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

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