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2-Methoxyethyl acrylate

Names

[ CAS No. ]:
3121-61-7

[ Name ]:
2-Methoxyethyl acrylate

[Synonym ]:
Ethylene Glycol Monomethyl Ether Acrylate
n-methoxyethyl acrylate
Acrylic Acid 2-Methoxyethyl Ester
Ethylene Glycol Methyl Ether Acrylate
Methyl cellosolve acrylate
Ethylene glycol methyl ether acrylate,stabilized
acrylic acid 2-methoxy-ethyl ester
EINECS 221-499-3
2-Methoxyethoxy acrylate
2-Propenoic acid,2-methoxyethyl ester
2-Methoxyethanol,acrylate
2-METHOXYETHYL ACRYLATE
1-Acryloyloxy-2-methoxy-aethan
Methoxyethyl acrylate
MFCD00048149
Sipomer MCA

Chemical & Physical Properties

[ Density]:
1.012 g/mL at 25 °C(lit.)

[ Boiling Point ]:
56 °C12 mm Hg(lit.)

[ Melting Point ]:
-30°C

[ Molecular Formula ]:
C6H10O3

[ Molecular Weight ]:
130.14200

[ Flash Point ]:
60 ºC

[ Exact Mass ]:
130.06300

[ PSA ]:
35.53000

[ LogP ]:
0.36200

[ Index of Refraction ]:
n20/D 1.427(lit.)

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
KL6000000
CHEMICAL NAME :
Ethanol, 2-methoxy-, acrylate
CAS REGISTRY NUMBER :
3121-61-7
BEILSTEIN REFERENCE NO. :
1754333
LAST UPDATED :
199710
DATA ITEMS CITED :
9
MOLECULAR FORMULA :
C6-H10-O3
MOLECULAR WEIGHT :
130.16
WISWESSER LINE NOTATION :
1U1VO2O1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Open irritation test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 9/17/1969 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
810 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 9/17/1969
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
500 ppm/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 9/17/1969
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
250 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 9/17/1969 ** REPRODUCTIVE DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
5200 mg/kg
SEX/DURATION :
female 7-14 day(s) after conception
TOXIC EFFECTS :
Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants)
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: PB86-197605
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
5200 mg/kg
SEX/DURATION :
female 6-13 day(s) after conception
TOXIC EFFECTS :
Reproductive - Fertility - litter size (e.g. # fetuses per litter; measured before birth)
REFERENCE :
TCMUD8 Teratogenesis, Carcinogenesis, and Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.1- 1980- Volume(issue)/page/year: 7,29,1987 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X7024 No. of Facilities: 4 (estimated) No. of Industries: 1 No. of Occupations: 14 No. of Employees: 1220 (estimated)

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS06, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H226-H302-H311 + H331-H314-H317-H360FD-H373-H412

[ Precautionary Statements ]:
P201-P280-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338-P308 + P313-P403 + P233

[ Target Organs ]:
Blood, Epididymus, Testes

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T:Toxic;

[ Risk Phrases ]:
R20/22;R24;R60;R61

[ Safety Phrases ]:
S16-S26-S36/37/39-S45-S53

[ RIDADR ]:
UN 1992 3/PG 3

[ WGK Germany ]:
1

[ RTECS ]:
KL6000000

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1

[ HS Code ]:
29161290

Synthetic Route

Precursor & DownStream

Customs

[ HS Code ]: 2916129000

[ Summary ]:
2916129000 other esters of acrylic acid VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

RAFT copolymerization of itaconic anhydride and 2-methoxyethyl acrylate: a multifunctional scaffold for preparation of “clickable” gold nanoparticles. Javakhishvili I, et al.

Chem. Commun. (Camb.) 49 , 4803-4805, (2013)


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