2-bromo-3-methylbut-2-ene
Names
[ CAS No. ]:
3017-70-7
[ Name ]:
2-bromo-3-methylbut-2-ene
[Synonym ]:
bromotrimethylethylene
2-(bromomethyl)-2-butene
2-Bromo-3-methyl-2-butene
2-Butene,2-bromo-3-methyl
2-bromo-3-methylbutene
2-bromo-3-methyl-but-2-ene
MFCD00191852
Chemical & Physical Properties
[ Density]:
1.284 g/mL at 25ºC(lit.)
[ Boiling Point ]:
40ºC75 mm Hg(lit.)
[ Melting Point ]:
-106.7°C (estimate)
[ Molecular Formula ]:
C5H9Br
[ Molecular Weight ]:
149.02900
[ Flash Point ]:
77 °F
[ Exact Mass ]:
147.98900
[ LogP ]:
2.69510
[ Index of Refraction ]:
n20/D 1.474(lit.)
MSDS
Safety Information
[ Symbol ]:
GHS02, GHS06
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H226-H301
[ Precautionary Statements ]:
P301 + P310
[ Hazard Codes ]:
Xn: Harmful;
[ Risk Phrases ]:
10-22
[ Safety Phrases ]:
36/37
[ RIDADR ]:
UN 1992 3/PG 3
[ WGK Germany ]:
3
[ Packaging Group ]:
III
[ Hazard Class ]:
3.2
[ HS Code ]:
2903399090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2903399090
[ Summary ]:
2903399090. brominated,fluorinated or iodinated derivatives of acyclic hydrocarbons. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%
Articles
Nat. Commun. 4 , 2352, (2013)
Pipecolidepsin A is a head-to-side-chain cyclodepsipeptide isolated from the marine sponge Homophymia lamellosa. This compound shows relevant cytotoxic activity in three human tumour cell lines and ha...
Copper-catalyzed halogen exchange in aryl halides: an aromatic Finkelstein reaction.J. Am. Chem. Soc. 124(50) , 14844-5, (2002)
A mild and general method for the conversion of aryl, heteroaryl, and vinyl bromides into the corresponding iodides was developed utilizing a catalyst system comprising 5 mol % of CuI and 10 mol % of ...
Palladium/di-1-adamantyl-n-butylphosphine-catalyzed reductive carbonylation of aryl and vinyl halides. Brennführer A, et al.Tetrahedron 63(27) , 6252-58, (2007)