结构式 物理化学性质
常用名 香芹酚 英文名 carvacrol
CAS号 499-75-2 分子量 150.21800
密度 0.976 g/mL at 20 °C(lit.) 沸点 236-237 °C(lit.)
分子式 C10H14O 熔点 3-4 °C(lit.)
MSDS香芹酚的MSDS|SDS|pdf下载 中文版 美版 闪点 224 °F
符号 GHS05 GHS07
GHS05, GHS07
信号词 Danger
 产品用途
【用途一】
用于配制香料、杀菌剂和消毒剂,作为香料用于牙膏、香皂等日用品,也用作食用香精
【用途二】
香料。主要供配制莳萝、丁子香、费蒿、肉、薄荷、香草香精等用。
【用途三】
用于配制香精,也用作杀菌剂和消毒剂。
更多

 物理化学性质
[ 密度 ]: 0.976 g/mL at 20 °C(lit.)
[ 沸点 ]: 236-237 °C(lit.)
[ 熔点 ]: 3-4 °C(lit.)
[ 分子式 ]: C10H14O
[ 分子量 ]: 150.21800
[ 闪点 ]: 224 °F
[ 精确质量 ]: 150.10400
[ PSA ]: 20.23000
[ LogP ]: 2.82400
[ 外观性状 ]: 无色或淡黄色液体
[ 折射率 ]: n20/D 1.522(lit.)
[ 储存条件 ]: 库房低温通风干燥,防明火,高温,与氧化剂分开存放
[ 水溶解性 ]: Insoluble
 MSDS
香芹酚 修改号码:5

模块1. 化学品
产品名称: Carvacrol
修改号码: 5

模块2. 危险性概述
GHS分类
 物理性危害未分类
 健康危害
急性毒性(经口) 第4级
皮肤腐蚀/刺激 第2级
严重损伤/刺激眼睛 2A类
 环境危害未分类
GHS标签元素
 图标或危害标志
 信号词警告
 危险描述吞咽有害。
造成皮肤刺激
造成严重眼刺激
 防范说明
[预防]使用本产品时切勿吃东西,喝水或吸烟。
处理后要彻底清洗双手。
穿戴防护手套/护目镜/防护面具。
[急救措施] 食入:若感不适,呼叫解毒中心/医生。漱口。
眼睛接触:用水小心清洗几分钟。如果方便,易操作,摘除隐形眼镜。继续冲洗。
眼睛接触:求医/就诊
皮肤接触:用大量肥皂和水轻轻洗。
若皮肤刺激:求医/就诊。
脱掉被污染的衣物,清洗后方可重新使用。
[废弃处置] 根据当地政府规定把物品/容器交与工业废弃处理机构。
香芹酚 修改号码:5

模块3. 成分/组成信息
单一物质/混和物单一物质
化学名(中文名):香芹酚
百分比: >95.0%(GC)
CAS编码: 499-75-2
俗名: Isothymol , 5-Isopropyl-o-cresol , 5-Isopropyl-2-methylphenol
分子式: C10H14O

模块4. 急救措施
吸入: 将受害者移到新鲜空气处,保持呼吸通畅,休息。若感不适请求医/就诊。
皮肤接触: 立即去除/脱掉所有被污染的衣物。用大量肥皂和水轻轻洗。
若皮肤刺激或发生皮疹:求医/就诊。
眼睛接触:用水小心清洗几分钟。如果方便,易操作,摘除隐形眼镜。继续清洗。
如果眼睛刺激:求医/就诊。
食入: 若感不适,呼叫解毒中心/医生。漱口。
紧急救助者的防护:救援者需要穿戴个人防护用品,比如橡胶手套和气密性护目镜。

模块5. 消防措施
合适的灭火剂:干粉,泡沫,二氧化碳
不适用的灭火剂:水(有可能扩大灾情。)
特定方法:从上风处灭火,根据周围环境选择合适的灭火方法。
非相关人员应该撤离至安全地方。
周围一旦着火:如果安全,移去可移动容器。
消防员的特殊防护用具:灭火时,一定要穿戴个人防护用品。

模块6. 泄漏应急处理
个人防护措施,防护用具, 使用个人防护用品。远离溢出物/泄露处并处在上风处。确保足够通风。
紧急措施:泄露区应该用安全带等圈起来,控制非相关人员进入。
环保措施:防止进入下水道。
控制和清洗的方法和材料:用合适的吸收剂(如:旧布,干砂,土,锯屑)吸收泄漏物。一旦大量泄漏,筑堤控
制。附着物或收集物应该立即根据合适的法律法规废弃处置。

模块7. 操作处置与储存
处理
技术措施:在通风良好处进行处理。穿戴合适的防护用具。防止烟雾产生。处理后彻底清洗双手
和脸。
注意事项:如果蒸气或浮质产生,使用通风、局部排气。
操作处置注意事项:避免接触皮肤、眼睛和衣物。
贮存
储存条件:保持容器密闭。存放于凉爽、阴暗处。
存放于惰性气体环境中。
远离不相容的材料比如氧化剂存放。
气敏
包装材料:依据法律。

模块8. 接触控制和个体防护
工程控制:尽可能安装封闭体系或局部排风系统,操作人员切勿直接接触。同时安装淋浴器和洗
眼器。
个人防护用品
 呼吸系统防护:防毒面具。依据当地和政府法规。
香芹酚 修改号码:5

模块8. 接触控制和个体防护
 手部防护:防护手套。
 眼睛防护:安全防护镜。如果情况需要,佩戴面具。
 皮肤和身体防护:防护服。如果情况需要,穿戴防护靴。

模块9. 理化特性
液体
外形(20°C):
外观:透明
颜色: 无色-黄色
气味:无资料
pH:无数据资料
熔点:无资料
沸点/沸程 238 °C
闪点: 100°C
爆炸特性
 爆炸下限:无资料
 爆炸上限:无资料
密度: 0.98
溶解度:
[水]无资料
[其他溶剂]无资料

模块10. 稳定性和反应性
化学稳定性:一般情况下稳定。
危险反应的可能性:未报道特殊反应性。
须避免接触的物质氧化剂
危险的分解产物: 一氧化碳, 二氧化碳

模块11. 毒理学信息
急性毒性: orl-cat LDLo:100 mg/kg
orl-rat LD50:810 mg/kg
对皮肤腐蚀或刺激:无资料
对眼睛严重损害或刺激:无资料
生殖细胞变异原性:无资料
致癌性:
IARC =无资料
NTP =无资料
生殖毒性:无资料
RTECS 号码: FI1225000

模块12. 生态学信息
生态毒性:
鱼类:无资料
甲壳类:无资料
藻类:无资料
残留性 / 降解性:无资料
潜在生物累积 (BCF):无资料
土壤中移动性
 log水分配系数:无资料
 土壤吸收系数 (Koc):无资料
香芹酚 修改号码:5

模块12. 生态学信息
 亨利定律无资料
constant(PaM3/mol):

模块13. 废弃处置
如果可能,回收处理。请咨询当地管理部门。建议在装有后燃和洗涤装置的化学焚烧炉中焚烧。废弃处置时请遵守
国家、地区和当地的所有法规。

模块14. 运输信息
联合国分类:与联合国分类标准不一致
UN编号:未列明

模块15. 法规信息
《危险化学品安全管理条例》(2002年1月26日国务院发布,2011年2月16日修订): 针对危险化学品的安全使用、
生产、储存、运输、装卸等方面均作了相应的规定。


模块16 - 其他信息
N/A
 毒性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
FI1225000
CHEMICAL NAME :
Carvacrol
CAS REGISTRY NUMBER :
499-75-2
BEILSTEIN REFERENCE NO. :
1860514
LAST UPDATED :
199701
DATA ITEMS CITED :
13
MOLECULAR FORMULA :
C10-H14-O
MOLECULAR WEIGHT :
150.24
WISWESSER LINE NOTATION :
QR B1 EY1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 17,743,1979 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
810 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 2,327,1964
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
73300 ug/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - ataxia
REFERENCE :
QJDRAZ Quarterly Journal of Crude Drug Research. (Lisse, Netherlands) V.1-19, 1961-81. For publisher information, see IJCREE. Volume(issue)/page/year: 19,1,1981
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
680 mg/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold
REFERENCE :
SIZSAR Sapporo Igaku Zasshi. Sapporo Medical Journal. (Sapporo Igaku Daigaku, Nishi-17-chome, Minami-1-jo, Chuo-ku, Sapporo 060, Japan) V.3- 1952- Volume(issue)/page/year: 3,73,1952
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
80 mg/kg
TOXIC EFFECTS :
Behavioral - sleep
REFERENCE :
JMCMAR Journal of Medicinal Chemistry. (American Chemical Soc., Distribution Office Dept. 223, POB POB 57136, West End Stn., Washington, DC 20037) V.6- 1963- Volume(issue)/page/year: 23,1350,1980
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
310 mg/kg
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
THERAP Therapie. (Doin, Editeurs, 8, Place de l'Odeon, F-75006 Paris, France) V.1- 1946- Volume(issue)/page/year: 3,109,1948
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - cat
DOSE/DURATION :
100 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
HBTXAC "Handbook of Toxicology," 4 vols., Philadelphia, W.B. Saunders Co., 1956-59 Volume(issue)/page/year: 5,46,1959
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
100 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AEPPAE Naunyn-Schmiedeberg's Archiv fuer Experimentelle Pathologie und Pharmakologie. (Berlin, Ger.) V.110-253, 1925-66. For publisher information, see NSAPCC. Volume(issue)/page/year: 161,196,1931
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
2700 mg/kg
TOXIC EFFECTS :
Skin and Appendages - dermatitis, other (after systemic exposure)
REFERENCE :
JAPMA8 Journal of the American Pharmaceutical Association, Scientific Edition. (Washington, DC) V.29-49, 1940-60. For publisher information, see JPMSAE. Volume(issue)/page/year: 38,366,1949
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
1 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
HBTXAC "Handbook of Toxicology," 4 vols., Philadelphia, W.B. Saunders Co., 1956-59 Volume(issue)/page/year: 5,46,1959
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Amphibian - frog
DOSE/DURATION :
75 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
HBTXAC "Handbook of Toxicology," 4 vols., Philadelphia, W.B. Saunders Co., 1956-59 Volume(issue)/page/year: 5,46,1959 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X5071 No. of Facilities: 1235 (estimated) No. of Industries: 6 No. of Occupations: 8 No. of Employees: 7449 (estimated) No. of Female Employees: 979 (estimated)
 安全信息
[ 符号 ]: GHS05 GHS07
GHS05, GHS07
[ 信号词 ]: Danger
[ 危害声明 ]: H302-H314
[ 警示性声明 ]: P280-P305 + P351 + P338-P310
[ 个人防护装备 ]: Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ 危害码 (欧洲) ]: C:Corrosive
[ 风险声明 (欧洲) ]: R22;R34
[ 安全声明 (欧洲) ]: S26-S36/37/39-S45
[ 危险品运输编码 ]: UN 3265 8/PG 3
[ WGK德国 ]: 3
[ RTECS号 ]: FI1225000
[ 包装等级 ]: III
[ 危险类别 ]: 8
[ 海关编码 ]: 2907199090
 合成线路

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~%

详细
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 制备
【方法一】
由富含香芹酚的天然精油用碱溶液处理,再用乙醚抽提或水蒸气蒸馏而得。
由对百里香酚经磺化后再经碱处理而得。
 海关
[ 海关编码 ]: 2907199090
[ 中文概述 ]: 2907199090 其他一元酚. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:5.5% 普通关税:30.0%
[申报要素 ]: 品名, 成分含量, 用途
[ Summary ]: 2907199090 other monophenols VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%
 文献53更多
Evidence for the involvement of descending pain-inhibitory mechanisms in the attenuation of cancer pain by carvacrol aided through a docking study.

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The present study evaluated the carvacrol (CARV) effect on hyperalgesia and nociception induced by sarcoma 180 (S180) in mice.Carvacrol treatment (12.5-50mg/kgs.c.) once daily for 15days was started 2...

Comparison of biological processes induced in HepG2 cells by tert-butyl hydroperoxide (t-BHP) and hydroperoxide (H2O2): The influence of carvacrol.

Mutat. Res. 757(1) , 15-22, (2013)

This paper presents comparisons of biological impacts of the oxidants H2O2 and t-BHP on human liver cells, and shows modulation of these effects by the phenolic compound carvacrol. To understand bette...

Activity of essential oil of Lippia triplinervis Gardner (Verbenaceae) on Rhipicephalus microplus (Acari: Ixodidae).

Parasitol. Res. 112(2) , 863-9, (2013)

The objective of this work was to characterize and investigate the acaricidal activity of the essential oil of the aerial parts of Lippia triplinervis at different concentrations on unengorged larvae ...