(η⁵-环戊二烯基)[N,N-二甲基-Ν'-(2-吡啶基亚甲基)丙烷-1,3-二胺]六氟磷酸钌

• 常用名: (η⁵-环戊二烯基)[N,N-二甲基-Ν'-(2-吡啶基亚甲基)丙烷-1,3-二胺]六氟磷酸钌
• 英文名: (η⁵-Cyclopentadienyl)[N,N-dimethyl-Ν′-(2-pyridinylmethylidene)propane-1,3-diamine]ruthenium hexafluorophosphate
• CAS号: 1603164-23-3
• 分子量: 502.4
• 密度: N/A
• 沸点: N/A
• 分子式: C₁₆H₁₇F₆N₃PRu
• 熔点: >180℃
• 闪点: N/A

用途

Description (η5-Cyclopentadienyl)[N,N-dimethyl-N′-(2-pyridinylmethylidene)propane-1,3-diamine]ruthenium hexafluorophosphate is also referred to as Herzon reductive hydration catalyst. Herzon reductive hydration catalyst is a half-sandwich ruthenium complex. It is a tridentate nitrogen-based ligand containing a hemilabile 3-(dimethylamino)propyl group. It participates in the conversion of terminal alkynes to linear alcohols.Catalyst mediates the transformation of alkynes to alcohols through ananti-Markovnikov addition. This reaction occurs at room temperature with the use of formic acid to assist in the reduction of the intermediate aldehyde to the corresponding alcohol. Description (η5-Cyclopentadienyl)[N,N-dimethyl-N′-(2-pyridinylmethylidene)propane-1,3-diamine]ruthenium hexafluorophosphate is also referred to as Herzon reductive hydration catalyst. Herzon reductive hydration catalyst is a half-sandwich ruthenium complex. It is a tridentate nitrogen-based ligand containing a hemilabile 3-(dimethylamino)propyl group. It participates in the conversion of terminal alkynes to linear alcohols.Catalyst mediates the transformation of alkynes to alcohols through ananti-Markovnikov addition. This reaction occurs at room temperature with the use of formic acid to assist in the reduction of the intermediate aldehyde to the corresponding alcohol.

名称

• 中文名: (η⁵-环戊二烯基)[N,N-二甲基-Ν'-(2-吡啶基亚甲基)丙烷-1,3-二胺]六氟磷酸钌
• 英文名: (η⁵-Cyclopentadienyl)[N,N-dimethyl-Ν′-(2-pyridinylmethylidene)propane-1,3-diamine]ruthenium hexafluorophosphate

物理化学性质

• 熔点: >180℃
• 分子式: C₁₆H₁₇F₆N₃PRu
• 分子量: 502.4

英文别名

• Herzon Reductive Hydration Catalyst